ECTS credits ECTS credits: 3
ECTS Hours Rules/Memories Student's work ECTS: 54 Hours of tutorials: 2 Expository Class: 12 Interactive Classroom: 7 Total: 75
Use languages Spanish, Galician
Type: Ordinary subject Master’s Degree RD 1393/2007 - 822/2021
Departments: Organic Chemistry
Areas: Organic Chemistry
Center Faculty of Chemistry
Call: Second Semester
Teaching: With teaching
Enrolment: Enrollable | 1st year (Yes)
At the end of the course, the student will be able to:
1.Understand the basis of catalytic cycles from the perspective of reaction coordinates and potential energy surfaces.
2.Grasp the synthetic applications of diverse bond-forming processes mediated by organometallic compounds.
3.Propose synthetic sequences with key disconnections based on organometallic synthetic processes.
Topic 1. Cross-coupling reactions and the Heck reaction.
Topic 2. Insertion reactions.
Topic 3. Reactions of allyl complexes.
Topic 4. Reactions of metal-alkene, alkyne, diene, and arene complexes.
Topic 5. Reactivity of metal carbenes.
Topic 6. C–H bond activation reactions.
BASIC BIBLIOGRAPHY
• Bates, R. Organic Synthesis Using Transition Metals, 2nd Ed.; Wiley: Chichester, UK, 2012.
• Hegedus, L. S. Transition Metals in the Synthesis of Complex Organic Molecules, 2nd Ed.; University Science Books: Sausalito, CA, 1999
COMPLEMENTARY BIBLIOGRAPHY.
• Luther, G. W. (2016) Reactivity of Transition Metal Complexes: Thermodynamics, Kinetics and Catalysis, in Inorganic Chemistry for Geochemistry and Environmental Sciences: Fundamentals and Applications, John Wiley & Sons, Ltd, Chichester, UK. Doi: 10.1002/9781118851432. Capítulo 9.
• Cybulski, A.; Moulijn, J. A.; Stankiewicz, A. (2010) Novel Concepts in Catalysis and Chemical Reactors: Improving the Efficiency for the Future. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. ISBN: 978-3-527-32469-9. Capítulo 1.
• Ananikov, V. P. (2015) Understanding Organometallic Reaction Mechanisms and Catalysis: Computational and Experimental Tools. Wiley-VCH Verlag GmbH & Co. KGaA. Published 2015 byWiley-VCH Verlag GmbH & Co. KGaA. Capítulo 9.
• Negishi, E., Ed. Handbook of Organopalladium Chemistry for Organic Synthesis; Wiley: New York, 2002
• De Meijere, A., Bräse, S., Oestreich, M. Metal-Catalyzed Cross-Coupling Reactions and More; Wiley-VCH: Weinheim, 2014.
• Beller, M., Bolm, C. Transition Metals for Organic Synthesis, 2nd Ed.; Wiley-VCH, Weinheim, 2004.
• Kazmaier, U. Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis, Springer-Verlag Berlin Heidelberg 2012.
• Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 4th Ed.; John Wiley & Sons, Wiley, 2005.
• Yu, J.-Q. Science of Synthesis: Catalytic Transformations via C-H Activation Vol. 1 & 2; Thieme.
BASIC AND GENERAL COMPETENCIES
CG2 – Identify relevant information from scientific literature using appropriate channels and integrate this information to formulate and contextualize a research topic.
CG5 – Use scientific terminology in English to discuss experimental results within the context of the chemistry profession.
CG6 – Correctly apply new information-gathering and organization technologies to solve problems in professional practice.
CB6 – Possess and understand knowledge that provides a foundation for originality in developing and/or applying ideas, often in a research context.
CB7 – Students should be able to apply acquired knowledge and problem-solving skills in new or unfamiliar environments within broader (or multidisciplinary) contexts related to their field of study.
CB9 – Students should be able to communicate their conclusions—along with the underlying knowledge and reasoning—to both specialized and non-specialized audiences in a clear and unambiguous manner.
CB10 – Students should develop learning skills that enable them to continue studying in a largely self-directed and autonomous manner.
TRANSVERSAL COMPETENCIES
CT1 – Prepare, write, and publicly defend scientific and technical reports.
CT3 – Work autonomously and efficiently in daily research or professional practice.
CT4 – Value quality and continuous improvement, acting with rigor, responsibility, and professional ethics.
SPECIFIC COMPETENCIES
CE1 – Define specialized concepts, principles, theories, and facts from different areas of Chemistry.
CE2 – Propose alternatives for solving complex chemical problems across various chemical disciplines.
CE4 – Innovate in synthesis and chemical analysis methods related to different areas of Chemistry.
CE6 – Design processes involving the treatment or disposal of hazardous chemical products.
CE8 – Analyze and independently utilize data obtained from complex laboratory experiments, relating them to appropriate chemical, physical, or biological techniques, including the use of primary bibliographic sources.
MD1. Face-to-face theoretical classes. Lecture-based classes (use of blackboard, computer, projector), complemented with virtual teaching tools.
MD3. Seminars conducted by the Master's own faculty or invited professionals from industry, government, or other universities. Interactive sessions related to different subjects with debates and exchanges of opinions with students.
MD4. Resolution of practical exercises (problems, test-type questions, interpretation and processing of information, evaluation of scientific publications, etc.).
MD5. Individual tutorials in small groups.
MD6. Completion of assignments, both individually and in groups, on scientific topics related to the different subjects of the Master's program.
MD7. Oral presentation of assignments, reports, etc., including debate with teachers and students.
MD8. Use of specialized software and internet. Online teaching support (Virtual Campus).
MD10. Independent study based on different sources of information.
MD11. Completion of different tests to verify the acquisition of both theoretical and practical knowledge, as well as skills and attitudes.
The evaluation of this subject will be carried out through continuous assessment and a final exam.
Final exam. [60% of the grade, assessed competencies: CG6, CB6, CT3, CE1, CE2, CE4, CE6]
Problem-solving and practical cases. [15% of the grade, assessed competencies: CG2, CG5, CB7, CE2, CE4, CE6]
Oral presentation (assignments, reports, problem-solving and practical cases). [5% of the grade, competencies: CG2, CB9, CT1, CE8]
Attendance and participation. [10% of the grade, competencies: CB10, CT4]
Continuous student assessment through oral questions and tasks during the course. [10%, competencies: CG2, CT4]
"In cases of fraudulent completion of exercises or assessments, the provisions of the 'Regulations for the Assessment of Academic Performance and Grade Review' shall apply."
CLASSROOM-BASED WORK:
Lectures in large groups: 12 h. Seminars: 7 h. Scheduled tutorials: 2 h. Total classroom-based work: 21 h.
STUDENT'S INDEPENDENT WORK:
Preparation of assignments and directed tasks: 18 h. Student's personal study: 36 h. Total student's independent work: 54 h
21 h classroom-based work + 54 h independent work = 75 total hours
Study the subject progressively by completing the proposed exercises for the seminars.
CONTACT INFO:
Moisés Gulías Costa
ext 15790
moises.gulias [at] usc.es (moises[dot]gulias[at]usc[dot]es)
Ciqus building - Floor 3 - Office 5
Moises Gulias Costa
Coordinador/a- Department
- Organic Chemistry
- Area
- Organic Chemistry
- Phone
- 881815790
- moises.gulias [at] usc.es
- Category
- Professor: University Lecturer
| Wednesday | |||
|---|---|---|---|
| 11:00-13:00 | Grupo /CLE_01 | Spanish | Classroom 2.12 |