Juan Crugeiras Martínez

Profesor Titular

Tel.:

+34 881 814 430

juan.crugeiras@usc.es

Research unit:

Biophysical Chemistry

Biographical sketch

Academic career

Since 2001	Associate Professor of Physical Chemistry, University of Santiago de Compostela (USC)
1998-2001	Provisional Associate Professor of Physical Chemistry, USC
1993-1998	Assistant Profesor of Physical Chemistry, USC

Postdoctorate

1997	Postdoctoral stay at the Chemistry Department of the University at Buffalo, Buffalo-NY-USA
	Research on enolization reactions catalyzed by metal ions and chemical reactivity and chemical reactivity, with John P. Richard.
Mar-Nov 1994	Postdoctoral stay at the Chemistry Department of Newcastle University, Newcastle upon Tyne, UK.
	Investigation of the mechanism of solvolysis of trityl amines and trityl alcohols, with Howard Maskill.

Publications

Halogen transfer through halogen bonds in halogen-bound ammonia homodimers

Juan Crugeiras, Ana Ríos

Physical Chemistry Chemical Physics 2016, 18, 30961–30971. DOI: 10.1039/C6CP06182F

Reactions of chlorination with tert-butyl hypochlorite (^TBuOCl)

Cristina Pastoriza, Juan Manuel Antelo, Juan Crugeiras

Journal of Physical Organic Chemistry 2014, 27, 952–959. DOI: 10.1002/poc.3377

Kinetic study of the formation of N-chloro compounds using N-chlorosuccinimide

Cristina Pastoriza, Juan Manuel Antelo, Juan Crugeiras, Angeles Peña-Gallego

Journal of Physical Organic Chemistry 2014, 27, 407–418. DOI: 10.1002/poc.3278

Oxidation of Bromide by Tert-Butyl Hypochlorite

Cristina Pastoriza, Juan Manuel Antelo, Juan Crugeiras

International Journal of Chemical Kinetics 2013, 45, 629–637. DOI:10.1002/kin.20799

Use of N-chloro-N-methyl-p-toluenesulfonamide in N-chlorination reactions

Cristina Pastoriza, Juan Manuel Antelo, Juan Crugeiras

Journal of Physical Organic Chemistry 2013, 26, 551–559. DOI: 10.1002/poc.3127

Substituent Effects on Electrophilic Catalysis by the Carbonyl Group: Anatomy of the Rate Acceleration for PLP-Catalyzed Deprotonation of Glycine

Juan Crugeiras, Ana Ríos, Enrique Riveiros, and John P. Richard

Journal of the American Chemical Society 2011, 133, 3173–3183

The PLP cofactor: Lessons from studies on model reactions

John P. Richard, Tina L. Amyes, Juan Crugeiras, Ana Ríos

Biochimica et Biophysica Acta 2011, 1814, 1419–1425

DFT and AIM Study of the Protonation of Nitrous Acid and the pKa of Nitrous Acidium Ion

Juan Crugeiras, Ana Ríos, and Howard Maskill

The Journal of Physical Chemistry A 2011, 115, 12357–12363

Nitrosation of dialkylhydroxylamines, and computational and NMR investigations of the interconversion of conformational isomers of N-nitrosodimethylhydroxylamine

Juan Crugeiras, Howard Maskill, William MacFarlane, Iain D. Menneer, Ana Ríos, Miguel A. Ríos

Journal of Physical Organic Chemistry 2011, 24, 162–171

Acid-catalysed chlorine transfer from N-chloramines to iodide ion: experimental evidence for a predicted change in mechanism

Paula Calvo, Juan Crugeiras and Ana Ríos

Organic & Biomolecular Chemistry 2010, 8, 4137–4142

Substituent Effects on the Thermodynamic Stability of Imines Formed from Glycine and Aromatic Aldehydes: Implications for the Catalytic Activity of Pyridoxal-5'-phosphate

Juan Crugeiras, Ana Ríos, Enrique Riveiros, and John P. Richard

Journal of the American Chemical Society 2009, 131, 15815–15824

Pyridoxal 5'-Phosphate: Electrophilic Catalyst Extraordinaire

John P. Richard, Tina L. Amyes, Juan Crugeiras, Ana Ríos

Current Opinion in Chemical Biology 2009, 13, 475-483

Kinetic and Thermodynamic Barriers to Chlorine Transfer between Amines in Aqueous Solution

Paula Calvo, Juan Crugeiras, Ana Ríos

The Journal of Organic Chemistry 2009, 74, 5381-5389

Glycine Enolates: The Effect of Formation of Iminium Ions to Simple Ketones on α-Amino Carbon Acidity and a Comparison with Pyridoxal Iminium Ions

Juan Crugeiras, Ana Ríos, Enrique Riveiros, Tina L. Amyes, and John P. Richard

Journal of the American Chemical Society 2008, 130, 2041-2050

Nucleophilic Substitution Reactions of N-Chloramines: Evidence for a Change in Mechanism with Increasing Nucleophile Reactivity

Paula Calvo, Juan Crugeiras, Ana Ríos, and Miguel A. Ríos

The Journal of Organic Chemistry 2007, 72, 3171-3178

Carbon Acidity of the α-Pyridinium Carbon of a Pyridoxamine Analog

Juan Crugeiras, Ana Ríos, Tina L. Amyes and John P. Richard

Organic & Biomolecular Chemistry 2005, 3, 2145-2149