Palladium-Catalyzed [5+2] Rollover Annulation of 1-Benzylpyrazoles with Alkynes: A Direct Entry to Tricyclic 2-Benzazapines

Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative a-C-H Allylation of Alicyclic Amines

Enantioenriched α-Vinyl 1,4-Benzodiazepines and 1,4-Benzoxazepines via Enantioselective Rhodium-Catalyzed Hydrofunctionalizations of Alkynes and Allenes

Recent Advances in Transition‐Metal‐Catalyzed Oxidative Annulations to Benzazepines and Benzodiazepines

Cp*RuCl-Vinyl Carbenes: Two Faces and the Bifunctional Role in Catalytic Processes

Palladium-Catalyzed [5 + 2] Heteroannulation of Phenethylamides with 1,3-Dienes to Dopaminergic 3‑Benzazepines

Ruthenium-Catalyzed Oxidative Amidation of Alkynes to Amides

Copper(I)-Catalyzed Tandem Carboarylation/Cyclization of Alkynyl Phosphonates with Diaryliodonium Salts

N‑Doped Cationic PAHs by Rh(III)-Catalyzed Double C−H Activation and Annulation of 2‑Arylbenzimidazoles with Alkynes

Metal-Catalyzed Cyclizations to Pyran and Oxazine Derivatives

Tandem Long Distance Chain-Walking/Cyclization via RuH2(CO)(PPh3)3/Brønsted Acid Catalysis: Entry to Aromatic Oxazaheterocycles

Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines

Nucleophilic Addition of Amines to Ruthenium Carbenes: ortho-(Alkynyloxy)benzylamine Cyclizations towards 1,3-Benzoxazines

One-step Chemoselective Conversion of Tetrahydropyranyl Ethers to Silyl-Protected Alcohols

Vinyl Dihydropyrans and Dihydrooxazines from Cyclizations of Catalytic Ruthenium Carbenes Derived from Alkynals and Alkynones

Rh(III)-Catalyzed Tandem C-H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

Formation of Indoles, Dihydroisoquinolines, and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations

Cross-Coupling Reactions of Organosilicon Compounds in the Stereocontrolled Synthesis of Retinoids

Ru-Catalyzed Heteroannulation to Indoles, Dihydroisoquinolines, and Dihydroquinolines

Ruthenium-Catalyzed Cycloisomerization of Aromatic Homo- and, Bis-Homopropargylic Amines/Amides: Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines

Ruthenium-Catalyzed Heteroannulation Route to Benzofurans and Isochromenes

Cycloisomerization of Aromatic Homo and Bis-homopropargylic Alcohols via Catalytic Ru Vinylidenes: Formation of Benzofurans and Isochromenes

6πe− versus 8πe− Electrocyclization of 1-Aryl- and Heteroaryl-Substituted (1Z,3Z)-1,3,5-Hexatrienes: A Matter of Aromaticity

CpRuCl- and CpCo-catalyzed or mediated cyclotrimerizations of alkynes and [2+2+2] cycloadditions of alkynes to alkenes: A comparative DFT study

Recent advances in the synthesis of pyridines by transition-metal-catalyzed [2+2+2] cycloaddition

New cyclizations via catalytic ruthenium vinylidenes

Acid-catalyzed cyclization of acyliminium ions derived from allenamides. A new entry to protoberberines

Highly convergent, stereoespecific synthesis of 11-cis-retinoids by metal-catalyzed cross-coupling reactions of (Z)-1-alkenylmetals

Ru-catalyzed cyclization of terminal alkynals to cycloalkenes

Pericyclic reactions involving catalytic metal-vinylidenes

Synthesis of marine polyacetylenes callyberines A-C by transition-metal-catalyzed cross-coupling reaction to sp centers

Synthesis of N-heteroaryl retinals and their artificial baceteriorhodopsins

Synthesis of carbazoles from ynamides by intramolecular dehydro Diels-Alder reactions

Intramolecular formal [4+2] cycloaddition reactions of secondary and tertiary aryldiacetylene alcohols

Rearrangement of cyclic allenes via 1,2-dehydro[10]annulenes: Intramolecular dehydro Diels-Alder of 3-(trimethylsilyl)propiolamides

Scope of Ru (II)-catalyzed synthesis of pyridines from alkynes and nitriles

Construction of pyridine rings by metal-mediated [2+2+2] cycloaddition

Synthesis of the tetracyclic core of anthracycline antibiotics by an intramolecular dehydro Diels-Alder approach

Cylic allene intermediates in intramolecular dehydro Diels-Alder reactions: Labeling and theoretical cycloaromatization studies

Regiocontrolled one-step synthesis of 3,3’-disubstituted 2,2’-bipyridine ligands by cobalt(I)-catalyzed [2+2+2] cyclotrimerization

Synthesis of fused rings at a pivotal nitrogen: tandem Heck reactions of N-vinyl-2-iodobenzamides

One-step synthesis of spiropyridines, a novel class of C2-symmetric chiral ligands, by cobalt(I)-catalyzed [2+2+2] cycloadditions between bis-alkynenitriles and alkynes

Regioselective synthesis of isoquino[1,2-b][3]benzazepines (homoprotoberberines) through 11-membered-ring stilbene lactams obtained by radical macrocyclization

One-step synthesis of symmetrical 3,3’-substituted 2,2’-bipyridine ligands by cobalt(I)-catalyzed [2+2+2] cycloadditions

Synthesis of dibenzodiynes: exceptionally easy formation of a chrysene biradical

A radical cyclization approach to isoindolobenzazepines. Synthesis of Lennoxamine

Reactivity of isoquinoline alkaloids with benzyne

Intermolecular benzyne cycloaddition approach to aporphinoids. Total syntheses of norcepharadione B, cepharadione B, dehydroanonaine, duguenaine, dehydronornuciferine, pontevedrine, O-methylatheroline, lysicamine and alkaloid PO-3

The reaction of 1-alkyldihydroisoquinolines with benzyne. An unexpected entry to dibenzindolizines

The intermolecular benzyne cycloaddition approach to dehydronoraporphines and oxoaporphines. Total synthesis of PO-3