Palladium-Catalyzed [5+2] Rollover Annulation of 1-Benzylpyrazoles with Alkynes: A Direct Entry to Tricyclic 2-Benzazapines

Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative a-C-H Allylation of Alicyclic Amines

Enantioenriched α-Vinyl 1,4-Benzodiazepines and 1,4-Benzoxazepines via Enantioselective Rhodium-Catalyzed Hydrofunctionalizations of Alkynes and Allenes

Recent Advances in Transition‐Metal‐Catalyzed Oxidative Annulations to Benzazepines and Benzodiazepines

Cp*RuCl-Vinyl Carbenes: Two Faces and the Bifunctional Role in Catalytic Processes

Palladium-Catalyzed [5 + 2] Heteroannulation of Phenethylamides with 1,3-Dienes to Dopaminergic 3‑Benzazepines

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

Rh(III)-Catalyzed [5 + 2] Oxidative Annulation of Cyclic Arylguanidines and Alkynes to 1,3-Benzodiazepines. A Striking Mechanistic Proposal from DFT

Vinyl Ruthenium Carbenes: Valuable Intermediates in Catalysis

[2 + 1] Cycloaddition of Catalytic Ruthenium Vinyl Carbenes: A Stereoselective Controlled Access to (Z)- and (E)-Vinyl Epoxypyrrolidines

Synthesis of Dihydroindolo[2,3-c]carbazole as Potential Telomerase Inhibitor

DFT and Kinetic Monte Carlo Study of TMS-Substituted Ruthenium Vinyl Carbenes: Key Intermediates for Stereoselective Cyclizations

Rh(III)-catalyzed [5+1] oxidative cycloaddition of arylguanidines with alkynes: a novel access to C4-disubstituted 1,4-dihydroquinazolin-2-amines

Catalytic Transformations of Alkynes via Ruthenium Vinylidene and Allenylidene Intermediates

Dihydrobiphenylenes through Ruthenium-Catalyzed [2+2+2] Cycloadditions of ortho-Alkenylarylacetylenes with Alkynes

Tandem Brönsted Acid Promoted and Nazarov Carbocyclizations on Enyne Acetals to Hydroazulenones

Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds

Ruthenium-Catalyzed Cycloisomerization of Aromatic Homo- and, Bis-Homopropargylic Amines/Amides: Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines

Ruthenium-Catalyzed Heteroannulation Route to Benzofurans and Isochromenes

Cycloisomerization of Aromatic Homo and Bis-homopropargylic Alcohols via Catalytic Ru Vinylidenes: Formation of Benzofurans and Isochromenes

6πe− versus 8πe− Electrocyclization of 1-Aryl- and Heteroaryl-Substituted (1Z,3Z)-1,3,5-Hexatrienes: A Matter of Aromaticity

Recent Advances in “Formal” Ruthenium-Catalyzed [2+2+2] Cycloaddition Reactions of Diynes to Alkenes

“Formal” and standard ruthenium-catalyzed [2+2+2] cycloaddition reaction of 1,6- diynes to alkenes: A mechanistic density functional study

Ruthenium-catalyzed decarbonylative cyclization of 1,6-diynes

A new Ru-catalyzed cascade reaction forming polycyclic cyclohexadienes from 1,6-diynes and alkenes

Assignment of the absolute conficuration of (+)-5,5’,6,6’-tetrahydro-7,7’-spiro[7Hcylopenta[b]pyridine], a new inherently chiral spiropyridine, by a nonempirical analysis of its circular dichroism spectrum

Diastereoselective remote C-H activation by hydroboration

Construction of pyridine rings by metal-mediated [2+2+2] cycloaddition

Mechanism and applications of the remote C-H activation of phenyl substituted alkenes by BH3.THF

Remote C-H activation of phenyl-substituted alkenes by BH3-THF: mechanism and applications

Selective transformations mediated by main-group organometallics

One-step synthesis of symmetrical 3,3’-substituted 2,2’-bipyridine ligands by cobalt(I)-catalyzed [2+2+2] cycloadditions